Radiocarbon dating is especially good for determining the age of sites occupied within the last 26,000 years or so (but has the potential for sites over 50,000), can be used on carbon-based materials (organic or inorganic), and can be accurate to within ±30-50 years.Probably the most important factor to consider when using radiocarbon dating is if external factors, whether through artificial contamination, animal disturbance, or human negligence, contributed to any errors in the determinations.For example, rootlet intrusion, soil type (e.g., limestone carbonates), and handling of the specimens in the field or lab (e.g., accidental introduction of tobacco ash, hair, or fibers) can all potentially affect the age of a sample.
Shell may succumb to isotopic exchange if it interacts with carbon from percolating ground acids or recrystallization when shell aragonite transforms to calcite and involves the exchange of modern calcite.The surrounding environment can also influence radiocarbon ages.The introduction of "old" or "artificial" carbon into the atmosphere (i.e., the "Suess Effect" and "Atom Bomb Effect", respectively) can influence the ages of dates making them appear older or younger than they actually are. The Radiocarbon Revolution Since its development by Willard Libby in the 1940s, radiocarbon (14C) dating has become one of the most essential tools in archaeology.Radiocarbon dating was the first chronometric technique widely available to archaeologists and was especially useful because it allowed researchers to directly date the panoply of organic remains often found in archaeological sites including artifacts made from bone, shell, wood, and other carbon based materials.
In contrast to relative dating techniques whereby artifacts were simply designated as "older" or "younger" than other cultural remains based on the presence of fossils or stratigraphic position, 14C dating provided an easy and increasingly accessible way for archaeologists to construct chronologies of human behavior and examine temporal changes through time at a finer scale than what had previously been possible.The application of Accelerator Mass Spectrometry (AMS) for radiocarbon dating in the late 1970s was also a major achievement.Compared to conventional radiocarbon techniques such as Libby's solid carbon counting, the gas counting method popular in the mid-1950s, or liquid scintillation (LS) counting, AMS permitted the dating of much smaller sized samples with even greater precision.Regardless of the particular 14C technique used, the value of this tool for archaeology has clearly been appreciated.Desmond Clark (1979:7) observed that without radiocarbon dating "we would still be foundering in a sea of imprecisions sometime bred of inspired guesswork but more often of imaginative speculation." And as Colin Renfrew (1973) aptly noted over 30 years ago, the "Radiocarbon Revolution" transformed how archaeologists could interpret the past and track cultural changes through a period in human history where we see among other things the massive migration of peoples settling virtually every major region of the world, the transition from hunting and gathering to more intensive forms of food production, and the rise of city-states.However, as with any dating technique there are limits to the kinds of things that can be satisfactorily dated, levels of precision and accuracy, age range constraints, and different levels of susceptibility to contamination.